Synthesis and characterization of (Mo0.52V0.38W0.1)2O5 used as a catalyst in the oxidative dehydrogenation of ethane

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Descripción: Abstract: This work presents a study of mixed molybdenum vanadium and tungsten oxides applied to oxidative dehydrogenation of ethane (ODE). Different oxides were prepared by a microwave-assisted hydrothermal method using oxalic acid as a reducing agent to obtain a crystalline phase of composition (Mo0.52V0.38W0.1)2O5. The materials were studied by XRF, BET, X-ray poder diffraction (XRD), transmission electron microscopy, IR, UV–Vis, TPR-H2 and XPS spectroscopy. The structure with space group C2/m is closely related to that of R–Nb2O5 with cell parameters a ¼ 1215.1 p.m., b ¼ 374.2 p.m., c ¼ 402.0 p.m., and ? ¼ 90.70. This phase is stable under reaction and active and selective to ethylene in the ODE reaction. Comparison with the literature indicates that R–Nb2O5-type matrices constitute an alternative to Mo5O14-type oxides to control the selectivity of active species in ODE.
Citación recomendada (normas APA)
: Juan Francisco; La Salvia García Valencia, "Synthesis and characterization of (Mo0.52V0.38W0.1)2O5 used as a catalyst in the oxidative dehydrogenation of ethane", Colombia:Journal of Solid State Chemistry, 2022. Consultado en línea en la Biblioteca Digital de Bogotá (https://www.bibliotecadigitaldebogota.gov.co/resources/3711724/), el día 2025-05-20.

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