Abstract: Claystone degradation under the effect of freezing and thaw cycles represents a key aspect in the production of erodible material in mountain ranges. Erosion processes have numerous potential consequences such as dam filling, increment in slope instability, increase of badlands, among others. Due to the possible effects related to erosion, numerous research processes have been carried out following primarily experimental approaches based on both soil physical characteristics and mechanical properties. However, these have been based on a macroscopic scale. This document presents the development of a research process based on the implementation of numerical models aimed at representing the processes involved in freezing and thawing phenomena on porous media and their effect on potential changes in soil microfabric. A calibration and validation process of the proposed numerical models was carried out based on experimental measurements of the thermal behavior of soil samples subjected to freezing and thawing cycles. Using the numerical relationships found, a methodology for determining the soil water retention curve (SWRC) was established (as a first approximation) based on a quick and relatively simple freezing and thawing test under undrained conditions. Simultaneously, and following the main objective of the research, the microfabric state during cyclic freezing and thawing was established following the relationship between SWRC and pore size distribution (PSD), as well as the possible hysteresis between freezing and thawing processes. The significant effect of these thermodynamic processes on the state of the terrain, was identified particularly in regard to increased erodibility. One possible cause for particle detachment necessary for erosion processes to occur lies in the development of macroporosity along with the existence of gaps between pore families in the PSD. This behavior was observed through the developed numerical processes. The combined effect of freezing and thawing cycles leads to an increase in soil erodibility. Finally, though a constitutive model-based approach, the cryogenic suction paths associated with freezing and thawing processes under the modification of the soil’s microstructure were established. A final perspective to soil's mechanical degradation is presented in terms of the hydraulic work associated with the cryogenic suction paths developed within the soil mass. Both the progressive evolution of the microstructure (through PSD) and the values of hydraulic work associated with each cycle show an attenuation in the incremental change as the cycles continue. Due to the numerical nature of the approximations and the trends found, further cyclical laboratory tests should be carried out. However, these represent a novel approach to the degradation phenomenon as well as the effects associated with the soil water retention curve.

Abstract: This thesis examines the modeling of inorganic behavior on Twitter and its implications for media dynamics. Three approaches —userbased, activity-based, and text-based detection— are combined to gain insights that benefit journalism and civil organizations. Resumen: Esta tesis examina el modelado del comportamiento inorgánico en Twitter y sus implicaciones para las dinámicas mediáticas. Se combinan tres enfoques (detección basada en características del usuario, basada en su actividad y basada en el contenido textual que publica o con el que interactúa), para encontrar patrones que ayuden a periodistas y organizaciones civiles a entender el fenómeno. Esta es una primera valoración positiva del uso del Inteligencia Artificial para explorar relaciones complejas que tienen significancia cualitativa en el estudio del comportamiento inorgánico en Twitter más allá de la detección.

Abstract: The research explores the role of regional Planning in fostering sustainable development in Colombia's diverse Pacific economic, social, and environmentally challenging context. Regional Planning is a traditional process that aims to enhance competitiveness, infrastructure connectivity between territories, and economic growth while addressing contemporary priorities like sustainable development. In response to these challenges, the Administrative and Planning Region (RAP Pacífico) in 2016 was created as a cooperative entity encompassing Pacific departments. This initiative seeks to stimulate economic and social development while overcoming financial, technical, and capacity related constraints. RAP Pacífico, through its Regional Strategic Plan, approved in 2021, departs from conventional approaches by adopting a collaborative and multidimensional strategy involving local authorities, private enterprises, and civil society. This research examines its innovative design strategies under the social innovation theory and its alignment with sustainable development goals. Moreover, the analysis sheds light on the potential of incorporating innovative elements in Planning exercises addressing complex societal challenges and aiming for regional sustainable development within the public management context, particularly in developing nations.

Abstract: Material Adverse Change clauses (MAC clauses) are contractual provisions that are usually incorporated within M&A and debt finance transactions. However, the low number of disputes that have arisen regarding the interpretation and application of such provisions have raised concerns given the uncertainty of its application and construction by the courts. Although the doctrine of good faith has been regarded as alien to English Contract Law, in this dissertation that claim is challenged by exploring other dimensions of such principle through two Civil Law jurisdictions and two recent judgements in English Law concerning MAC clauses in the context of Loan Agreements. Resumen: Las cláusulas de Cambio Adverso Sustancial (MAC, por sus siglas en inglés) son disposiciones contractuales que generalmente se incorporan en transacciones de fusiones y adquisiciones, así como en transacciones de financiamiento de deuda. Sin embargo, la baja cantidad de disputas que han surgido respecto a la interpretación y aplicación de tales disposiciones ha generado preocupación dada la incertidumbre en su aplicación y construcción por parte de los tribunales. Aunque la doctrina de la buena fe ha sido considerada ajena al Derecho de Contratos inglés, en esta tesis se cuestiona esa afirmación al explorar otras dimensiones de dicho principio a través de dos jurisdicciones de Derecho Civil y dos sentencias recientes en el Derecho inglés relacionadas con cláusulas MAC en el contexto de Acuerdos de Préstamo.

Abstract: Risk analysis techniques help to identify threats, problems and anomalies in processes and systems that may affect the health and safety of employees, the environment, equipment reliability and normative compliance. In this thesis, a stochastic risk analysis with Monte Carlo simulation applied to FMECA (Failure Modes, Effects and Criticality Analysis) was performed for a specific model of wind turbine located in the Alpha Ventus offshore wind Park. Monte Carlo simulations provide the decisionmaker with a range of possible outcomes and the probabilities of occurrences of these results, that are derived mainly from the uncertainty associated to the subjectivity of judgement from a group of experts. As a supplementary method to the stochastic FMECA, Risk Assessments Matrix (RAM) was also used for bivariate distributions of Severity and Occurrence of the identified failure modes. The results obtained were compared to the results that would be normally obtained with a conventional FMECA and RAM and will serve in future steps to develop Risk-Based Inspection plans for this model of wind turbine in this offshore wind park.

Abstract: This dissertation explores how three applications of AI, namely classifiers, natural language processing and generative AI, have contributed and might contribute to the realisation of Richard Susskind’s predictions for the future of legal practice, as set in his 2023 book ‘Tomorrow’s Lawyers’. Besides reviewing Susskind’s predictions, it proposes a model to describe how lawyers work and uses it to identify existing uses of technology in the legal field. Also, it provides a general and non-technical approach to AI and its history and main features. With this context, it delves into the selected AI applications and explores how they work, their early legal applications, and their challenges. The research’s conclusion highlights the selected AI applications as powerful enablers for Susskind’s predictions. Moreover, how generative AI has the potential to disrupt the market of legal services and outperform lawyers in multiple tasks. A key insight refers to the latent market of underserved individuals, communities, and small and medium enterprises and how it offers an unbeatable opportunity for online-embedded generative AI-based legal services, which would improve access to legal services. Finally, this dissertation suggests an unavoidable shift in the general comprehension of the abbreviations ‘LL.M’ and ‘LLM’ within the legal field.

Abstract: With growing traffic demands and structural degradation accelerated by climate change, there is a critical need for continued advancement of concrete repair and strengthening technologies to enable extended bridge service life. Specifically, transitioning to cost-effective reinforced concrete (RC) retrofit strategies that further enhance durability under service loading conditions and minimize damage development under extreme hazard conditions, which are more probable to occur in longer-lasting concrete structures, are key elements of next-generation concrete bridges. This thesis explores the use of iron-based shape memory alloys (Fe-SMAs) as an active shear retrofit strategy for RC components. SMAs are a class of smart materials with the unique property of the shape memory effect, allowing them to fully recover plastic deformations when subsequently heated. By installing prestrained Fe-SMA strips and activating the shape memory effect, an active pressure can be introduced to help close cracks and apply a confining stress in the concrete. The primary objective is to evaluate the performance and practicality of Fe-SMA as an active shear strengthening technique in comparison to traditional methods such as external steel reinforcement and fibre-reinforced polymer (FRP) composites. The experimental phase of this study involved conducting push-off tests on RC specimens retrofitted with pre-deformed Fe-SMA strips. The goal was to assess the efficiency of active shear retrofitting. Additionally, finite element analysis (FEA) simulations were employed to model Fe SMA-retrofitted RC structures and investigate their behaviour under shear loading conditions. Key findings indicate that Fe-SMA retrofits, through transverse prestressing as part of the active retrofit strategy, contributed to notable improvements in the stiffness and strength of damaged RC components. Similar to passive retrofit methods, increased shear capacity was observed with higher levels of transverse reinforcement. Notably, combinations of substantial shear reinforcement ratios and elevated transverse prestressing provided the most significant gains in shear strength. Furthermore, the addition of prestressed Fe-SMA retrofits was found to effectively reduce shear crack widths and mitigate the progression of subsequent shear crack width growth. This study not only demonstrates the potential of Fe-SMA as a promising solution for active shear strengthening but also contributes to the development of future field-scale tests. The presence of Fe-SMA in damaged structures offers the prospect of multiple improvements, marking a significant advancement in the field of shear retrofitting.

Resumen: El estudio resalta la oportunidad para fortalecer la biodiversidad, especialmente a través de la enseñanza de las ciencias ambientales y biociencias con un impacto esperado en el aumento en los niveles de alfabetización científica y su relación bidireccional con la educación y la cultura ambiental en la sociedad colombiana, con foco de estudio e impacto en la población estudiantil de ciencias naturales, biología y educación ambiental en los tres niveles educativos, así como la comunidad académica de las áreas de bioeconomía, ecosistemas naturales y territorios sostenibles. Se realizó una revisión y selección de la literatura científica bajo criterios de inclusión y exclusión como el año de publicación, los idiomas, los países de publicación y/o ejecución del estudio y las bases de datos utilizadas. Así, se tuvieron en cuenta autores que publicaran trabajos de investigación cualitativa y cuantitativa tanto aplicada como no aplicada tales como Boff, Caamaño, Calixto Flores, García & Rodríguez, González González y López & Sánchez. Se encontraron numerosas tendencias, tensiones y limitaciones en la integración de los conceptos de educación ambiental, biodiversidad y alfabetización científica, que se presentan como desafíos en el qué, el para qué y la estructura de la educación ambiental; las definiciones y la enseñanza en la alfabetización científica y la complejidad y relevancia en la comprensión de la biodiversidad. Se hallaron herramientas y conceptualizaciones con un impacto positivo para la conservación de los ecosistemas naturales estratégicos del país como la transversalización de la educación ambiental en el currículo; y el uso sostenible de los recursos por parte de las comunidades y la resignificación y apropiación del ambiente dentro de la cultura de las regiones como las necesidades ambientales contextuales de las poblaciones alfabetizadas. Se resalta el abordaje amplio y complejo de la biodiversidad dentro de un planteamiento nuevo hacia una pedagogía ambiental.

Abstract: Pharmaceutical Compounds (PCs), are synthetic substances intensively consumed by humans and continuously released into the urban wastewater. Often, the removal of PCs from wastewater is found to be insufficient, or even absent if population is not connected to the sewage system and wastewater is directly emitted into the environment. In the last decades, the PCs have aroused special attention because they have been found in surface water at concentrations that can cause negative effects on the aquatic biota and environment. Studies employing PCs monitoring and modelling techniques on surface waters have been mainly conducted in developed countries, while studies in developing countries are still scarce. Attempting to fill this gap, this work focused specifically in Colombia, where the occurrence of PCs has not been thoroughly studied and monitoring plans are barely done due to high costs. This work employed the Exposure to Pharmaceuticals in the Environment (ePiE), a spatially distributed model only implemented and used in Europe, to predict concentrations of PCs in rivers and lakes by considering their consumption, fate and transport. So, it aimed to create a new ePiE model network taking as a case of study the prediction of Naproxen and Paracetamol in the Upper Catchment of the Cauca River, Colombia, an area with a different socio-economic and climatic conditions with respect to the European continent. The methodological approach included: a) data collection on PCs’ consumption, physicochemical properties and removal in Wastewater Treatment Plants (WWTPs); b) consolidation of geodata of the study area such as hydrology, hydrography, urban agglomeration and WWTPs location; c) model building by using the open-source software environment R; d) analysis of the model sensitivity to input parameters; e) model validation. The results showed that all concentration predictions deviate within a range of only one order of magnitude from measurements which is a remarkable result when dealing with such high uncertainties. In terms of magnitude prediction, for the worst-case scenario, Naproxen and Paracetamol were found to exceed the environmental standards thresholds in 9% and 1% of the model river network nodes respectively. Overall, this research aimed to assess the applicability of the ePiE model in estimating the presence of PCs in a subregion of Colombia, demonstrating that it is feasible to expand ePiE to other areas and giving insights about the spatial distribution of pharmaceuticals substances so hotspots can be identified and several scenarios can be built in future works.

Resumen: En este trabajo de fin de máster, se utiliza el edificio Lake Shore Drive Apartments de Mies Van der Rohe como punto de partida para desarrollar un proyecto básico y de ejecución de un edificio de 208 viviendas con garajes y trasteros el cual cumpla con las especificaciones del Código Técnico de la Edificación. Se aplican los conocimientos adquiridos durante el máster en Construcción y Tecnología Arquitectónicas para explorar sistemas estructurales más eficientes y lograr que el edificio sea sostenible, con un consumo de energía casi nulo. Esto se logra a través del acondicionamiento pasivo de su envolvente, así como de la implementación de las instalaciones necesarias para el correcto funcionamiento de la edificación. Además, se implementan sistemas que garanticen su comportamiento frente al fuego. De igual manera, se elabora un presupuesto que permita conocer la viabilidad de la construcción, así como su mantenimiento durante su ciclo de vida.